天然产物研究与开发 ›› 2018, Vol. 30 ›› Issue (2): 268-273.doi: 10.16333/j.1001-6880.2018.2.016

• 研究简报 • 上一篇    下一篇

ICP-OES法测定花锚和椭圆叶花锚中的21种矿物元素

李佩佩1,2,卢学峰1,叶润蓉1,周玉碧1,万丽娜1,2,孙菁1*   

  1. 1中国科学院西北高原生物研究所青海省青藏高原特色生物资源研究重点实验室,西宁 810008;2中国科学院大学,北京 100049
  • 出版日期:2018-02-28 发布日期:2018-02-28
  • 基金资助:

    青海省重点实验室发展建设专项(2017-ZJ-Y10);国家自然科学基金青年基金(81403051);青海省自然科学基金(2016-ZJ-955)

Determination of 21 Mineral Elements in Halenia corniculata and Halenia elliptica by ICP-OES


LI Pei-pei1,2, LU Xue-feng1, YE Run-rong1, ZHOU Yu-bi1, WAN Li-nan1,2, SUN Jing1*   


  1. 1Qinghai Key Laboratory of Qinghai-Tibet Plateau Biological Resource,Northwest Institute of Plateau Biology,Chinese Academy of Sciences,Xining 810008,China; 2University of Chinese Academy of Sciences,Beijing 100049,China
  • Online:2018-02-28 Published:2018-02-28

摘要: 本实验采用微波消解-电感耦合等离子体-发射光谱法(ICP-OES)测定了中国仅有的龙胆科花锚属的两个种花锚和椭圆叶花锚中21种矿物元素含量。实验中各元素相关系数r≥0.9990,线性关系良好,加标回收率在86%~106%之间,RSD ≤4.35%,具有较好的准确度和精确度。结果表明,花锚和椭圆叶花锚均含有丰富的矿物元素,尤以Ca、Mg、Fe含量最高。椭圆叶花锚中Ca、Mg含量较高,其Ca含量是花锚的1.6倍;Be、Cd、Co、Li、Mo、Pb、Sb、Tl 8种元素在二者中含量基本相同;其余11种元素在椭圆叶花锚中含量较低。结合标本采集地的土壤背景值,推测植物中元素含量与其所处生境有关。通过对两种花锚植物资源元素含量的比较分析,可为其深入研究与开发利用提供一定的参考。

关键词: 电感耦合等离子发射光谱, 花锚, 椭圆叶花锚, 微波消解, 矿物元素

Abstract: Twenty-one mineral elements of Halenia corniculata and H.elliptica were tested by ICP-OES in this study.H.corniculata and H.elliptica are the only existing species of genus Halenia (family:Gentianaceae) distributed in China.According to dates,the correlation coefficients are all greater than 0.9990,which showed a good linearity.The recovery rates were in the range of 86%-106% and the RSD were all below 4.35%,which indicated good accuracy and precision.The results showed that both of them contained rich mineral elements,especially Ca,Mg,Fe.The content of Ca,Mg in H.elliptica were higher than that in H.corniculata,especially Ca,which was 1.6 times as much as in H.corniculata.The 8 elements,namely Be,Cd,Co,Li,Mo,Pb,Sb,Tl,were almost equal in both plants.In addition,contents of rest elements in H.corniculata were higher than that of H.elliptica.Combined with corresponding background values of soil elements,it was concluded that the contents of elements were related to growing environment of plants.By comparing differences in elemental contents between H.corniculata and H.elliptica,it can provide some basis for further study and usage.

Key words: ICP-OES, Halenia corniculata, Halenia elliptica, microwave digestion, mineral elements

中图分类号: 

O657.3