猪殃殃挥发油化学成分的GC-MS分析

天然产物研究与开发 ›› 2010, Vol. 23 ›› Issue (6): 1031-1035.

猪殃殃挥发油化学成分的GC-MS分析

蔡小梅^{1, 2}，王道平²，杨娟^{2 *}

¹贵州大学生命科学学院药学系，贵阳 550025； ²贵州省中国科学院天然产物化学重点实验室，贵阳 550002

收稿日期:2009-03-09 出版日期:2011-01-10 发布日期:2011-10-19
通讯作者: linyj401@tom.com
基金资助:
973计划前期研究专项（2007CB516813）；贵州省中药现代化科技产业研究开发专项（黔科合中药专字[2006] 5041号）

Analysis of the Volatile Constituents of Galium aparine L. var. tenerum by GC-MS

CAI Xiao-mei^1,2 , WANG Dao-ping² , YANG Juan^2*

¹Department of Pharmacy, School of Life Sciences, Guizhou University, Guiyang 550025, China; ²The Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550002, China

Received:2009-03-09 Online:2011-01-10 Published:2011-10-19

摘要/Abstract

摘要：

利用水蒸气蒸馏法提取猪殃殃挥发油成分，进一步采用气相色谱-质谱（GC/MS）联用方法对其化学成分进行分析，共鉴定了110种主要成分（占挥发油总量的87.38%），主要为十六烷酸(13.88%)、芳樟醇(11.90%)、6,10,14-三甲基-2-十五烷酮( 8.79%)、3-乙基-1,4-己二烯(2.37%)、2-戊-呋喃(2.09%)、2-己烯醛(1.90%)、己醛(1.89%)、(Z)-香叶醇 (1.84%)和α-松油醇(1.83%)、植醇(1.81%) 等。110个化合物均为首次从猪殃殃植物中被发现。

关键词: 猪殃殃, GC-MS分析, 挥发油, 化学成分

Abstract:

The volatile oil from Galium aparine L. var. tenerum was extracted by steam distillation and analysed by GC-MS. As a result, one hundred and ten compounds have been identified The major compounds are n-hexadecanoic acid (13.88%), linalool (11.90%), 2-pentadecanone, 6,10,14-trimethyl (8.79%), 1,4-hexadiene, 3-ethyl- (2.37%), furan, 2-pentyl (2.09%), 2-hexenal (1.90%), hexanal (1.89%), (Z)-geraniol (1.84%), α-terpineol (1.83%), and phytol (1.81%). The identified constituents accounted for 87.38% of the total ion peak area. And all these compounds were detected from the volatile oil of this plant for the first time.

Key words: Galium aparine L. var. tenerum, GC-MS, volatile oil, chemical constituents

蔡小梅，王道平，杨娟. 猪殃殃挥发油化学成分的GC-MS分析[J]. 天然产物研究与开发, 2010, 23(6): 1031-1035.

CAI Xiao-Mei, WANG Dao-Ping, YANG Juan. Analysis of the Volatile Constituents of Galium aparine L. var. tenerum by GC-MS[J]. NATURAL PRODUCT RESEARCH AND DEVELOPMENT, 2010, 23(6): 1031-1035.

参考文献

1 Chinese Academy Of Sciences Editorial Board of Flora of China Series.Flora of China(中国植物志). Beijing:Science Press,1989.1990.
2 Wang YW(王永卫),Liu XH(刘秀华),Zhang DR(张登荣),et al.Research of the biological characteristics and control of Galium aparine.J School Shihezi Agronomy(石河子农学院学报),1991, 18(3):16-23.
3 Tang GZ(唐贵章),Xu YJ(许永久),Lang LT(梁龙坦),et al.Tests of the Herbicide control of the Galium aparinein the field of wheat.J Anhui Agric Sci(安徽农业科学),2006,34:1627-1653.
4 Wang TQ(王廷泉),Xia DC(夏代才),Liu SW(刘尚文),et al.Research of the biological characteristics and chemical control of the Galium aparine in the field of wheat.J Xi'nan Agric(西南农业学报),1990, 4:169-171.
5 Pan YZ(潘玉真),Zhang DX(张多贤),Hou CB(侯传本),et al.The preliminary report of the mixed use bensulfuron and triazole in order to control of Galium aparine in the field of wheat.J Chin Plant Protection Guide(中国植保导刊),2004,8:34-34.
6 Baser KHC,Ozek T,Kirimer N,et al.Composition of the essential oils of Galium aparine L.and Galium odoratum(L.) Scop. from Turkey.J Essent Oil Res(挥发油研究杂志),2004,16:305-307.
7 Cong PZ(丛浦珠),Su KM(苏克曼).Analytical chemistry handbook No.9 volumes(分析化学手册,第9分册).Beijing:Chemical Industry Press,2000:1091.
8 Heller SR,Milne GWA,EPA-NZH.Mass Spectrol Data(质谱光谱数据).Washington:US Government Printing Office,1978.2.
9 Hua Y(滑艳),Wang HQ(汪汉卿).Research of the chemical constituents of volatile oil of Seriphidhtm terrae-albae and suppressing the bacterial action.J Proprietary Chin Med(中成药),2007,29:754-756.
10 Liu XM(刘学民).Synthesis of isopropyl palmitate.J Flavour Fragrance Cosmetics(香精香料化妆品), 2004,6:14-16.
11 Liu Rui(刘睿),Gu QJ(谷强君),Cui CB(崔承彬).Chemical constituents of Schefflera venulosa and their antitumor activity.J Chin Tradit Herb Drugs(中华传统医药),2005,36:328-332.
12 Xu HY(徐红颖),Yu XM(禹晓梅),Liang YZ(梁逸曾),et al.Analysis of the volatile oil from Radix Isatidis by GC-MS.J Nat Prod Res Dev(天然产物研究与开发),2008,20:292-294.
13 Bi HP(毕和平),Han CR(韩长日),Liang ZY(梁振益),et al.Chemical constituents of volatile oil from the thin leaves of Spiraea japonica.J Plant Resources Environ (植物资源与环境学报),2006,15:71-73.
14 Yang YL(杨永利),Guo SJ(郭守军),Ma RJ(马瑞君),et al.Chemical constituents of volatile oil from Adenostemma lavenia.J Trop Subtropical Plants(热带亚热带植物学报),2007,15:355-358.
15 Zhu QJ(朱俊洁),Meng XY (孟祥颖),Wu Yin(乌垠),et al.Chemical constituents of volatile oil from the fruit,stems,leaves and tree trunks of Padus.J Anal Chem (分析化学),2005,33:1651-1618.

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