天然产物研究与开发 ›› 2011, Vol. 23 ›› Issue (1): 20-24.

• 研究论文 • 上一篇    下一篇

凹叶瑞香的化学成分研究

扈晓佳1,2,金慧子1,严 岚1,张卫东1,3*   

  1. 1上海交通大学药学院,上海 200240;2上海交通大学医学院药学系,上海 200280;3第二军医大学药学院,上海 200433
  • 收稿日期:2009-04-23 发布日期:2011-07-20
  • 通讯作者: wdzhangy@hotmail.com

Chemical Constituents of Daphne retusa

HU Xiao-jia1,2, JIN Hui-zi1, YAN Lan1, ZHANG Wei-dong1,3*   

  1. 1School of Pharmacy, Shanghai Jiao Tong University, Shanghai 200240, China; 2Medical School, Shanghai Jiao Tong University, Shanghai 200280, China; 3School of Pharmacy, Second Military Medical University, Shanghai 200433, China

  • Received:2009-04-23 Published:2011-07-20
  • Supported by:

    This research project was supported by the Scientific Foundation of Shanghai Committee of Science and Technology (08DZ19771302)

摘要:

从凹叶瑞香的乙酸乙酯部位分离得到14个化合物,经波理化性质及波谱数据分析分别鉴定为瑞香黄烷A(1),瑞香黄烷B(2),瑞香黄烷C(3),瑞香黄烷E(4),瑞香黄烷F(5),芫花素(6),芫根苷(7),4′,5-二羟基-3′,7-二甲氧基黄酮(8),瑞香新素(9),5′′-去甲氧基瑞香新素(10),左旋松脂酚(11),瑞香醇酮(12),紫丁香苷(13)和丁香醛(14)。其中化合物1~14均为首次从该植物中分离得到。

关键词: 凹叶瑞香, 化学成分, 瑞香黄烷, 黄酮, 木脂素

Abstract:

Fourteen compounds were isolated from the barks and stems of Daphne retusa. Their structures were identified as daphnodorin A (1), daphnodorin B (2), daphnodorin C (3), daphnodorin E (4), daphnodorin F (5), genkwanin (6), yuankanin (7), 4′,5-dihydroxy-3′,7-dimethoxyflavone (8), daphneticin (9), 5′′-demethoxydaphneticin (10), (–)-pinoresinol (11), daphneolon (12), syringin (13), and syringaldehyde (14) by spectroscopic analysis. All compounds were obtained from this plant for the first time.

Key words: Daphne retusa, chemical constituents, daphnodorin, flavonoid, lignan

中图分类号: 

R284.2 Q946.91