团花树皮的化学成分研究

天然产物研究与开发 ›› 2011, Vol. 23 ›› Issue (3): 393-398.

• 研究论文 • 下一篇

团花树皮的化学成分研究

徐晓俞^1,2，李尚真¹，宋启示^1*

¹中国科学院西双版纳热带植物园热带植物资源开放实验室，昆明 650223；²中国科学院研究生院，北京 100049

收稿日期:2010-12-22 出版日期:2011-06-25 发布日期:2011-08-08
通讯作者: songqs@xtbg.ac.cn
基金资助:
中国科学院知识创新工程重要方向项目子课题（KSCX2-YW-R-132），国家863项目子课题（2007AA021504）

Chemical Constituents of the Bark of Anthocephalus chinensis

XU Xiao-yu^1,2, LI Shang-zhen¹, SONG Qi-shi^1*

1Laboratory of Tropical Plant Resource Sciences, Xishuangbanna Tropical Botanical Garden, Chinese Academy of Sciences, Kunming 650223, China; 2Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Received:2010-12-22 Online:2011-06-25 Published:2011-08-08

摘要/Abstract

摘要：

采用硅胶、MCI和Sephadex LH-20层析方法对团花树皮的化学成分进行分离纯化，运用现代波谱技术鉴定了10个化合物：4-carboxy-3-hydroxy-5-methylphenyl 3-methoxy-4-hydroxy-5-methylbenzoate（1），谷甾醇-3-O-(6'-O-棕榈酰基）-β-D-葡萄糖苷（2），喹诺酸-3-O-α-L-鼠李糖苷（3），clethric acid（4），常春藤苷元（5），钩藤苷元 C（6），morolic acid（7），咖啡酸甲酯（8），卡丹宾（9）和3α-二氢卡丹宾（10）。其中化合物1为一个新的酚性成分，化合物2~8首次从该属植物中分离得到。

关键词: 团花, 树皮, 化学成分, 4-carboxy-3-hydroxy-5-methylphenyl 3-methoxy-4-hydroxy-5-methylbenzoate

Abstract:

Ten compounds were isolated and purified from the bark of Anthocephalus chinensis by column chromatography on silica gel, MCI and Sephadex LH-20, and their structures were elucidated as 4-carboxy-3-hydroxy-5-methylphenyl 3-methoxy-4-hydroxy-5-methylbenzoate (1), sitosterol-3-O-(6'-O-palmityl)-β-D-glucoside (2), quinovic acid-3-O-α-L-rhamnopyranoside (3), clethric acid (4), hederagenin (5), uncargenin C (6), morolic acid (7), caffeic acid methyl ester (8), cadambine (9), and 3α-dihydrocadambine (10) by modern spectroscopic methods. Compound 1 was a new phenolic compound, and compounds 2-8 were obtained from Anthocephalus plantsfor the first time.

Key words: Anthocephalus chinensis, bark , chemical constituent , 4-carboxy-3-hydroxy-5-methylphenyl 3-methoxy-4-hydroxy-5-methylbenzoate

中图分类号:

R284.2 Q946.91

徐晓俞，宋启示，李尚真. 团花树皮的化学成分研究[J]. 天然产物研究与开发, 2011, 23(3): 393-398.

XU Xiao-yu, LI Shang-zhen, SONG Qi-shi. Chemical Constituents of the Bark of Anthocephalus chinensis[J]. NATURAL PRODUCT RESEARCH AND DEVELOPMENT, 2011, 23(3): 393-398.

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团花树皮的化学成分研究

Chemical Constituents of the Bark of Anthocephalus chinensis

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