天然产物研究与开发 ›› 2014, Vol. 26 ›› Issue (11): 1793-1796.

• 研究简报 • 上一篇    下一篇

香樟叶化学成分的研究

孙崇鲁*,汤小蕾,周静峰,吴浩   

  1. 浙江医药高等专科学校,宁波 315100
  • 出版日期:2014-11-29 发布日期:2014-12-18

Study on Chemical Constituents of Cinnamomum Camphora Leaves

SUN Chong-lu*,TANG Xiao-lei, ZHOU Jing-feng, WU Hao   

  1. Zhejiang Pharmaceutical College,Ningbo Zhejiang 315100,China
  • Online:2014-11-29 Published:2014-12-18

摘要: 采用硅胶色谱柱层析、聚酰胺色谱柱层析、制备薄层色谱及其它分离手段从香樟叶(Cinnamomum camphora Leaves)70%乙醇提取中分离得到9个化合物, 根据化合物理化性质和波谱数据分别鉴定为:邻苯二甲酸二丁酯(1)、l-细辛脂素(2)、(8R,8′ R)-3,3′,4,4′-四甲氧基-9-氧代-8-8′,9-O-9′-木脂素(3)、槲皮素-3-Ο-β-D-葡萄糖苷(4)、山奈酚-3-O-β-芸香糖苷(5)、山柰酚-3-O-α-L-吡喃鼠李糖苷(6)、槲皮素3-Ο-α-L-鼠李糖苷(7)、芦丁(8)、异鼠李素-3-O-β-芸香糖苷(9)。其中化合物1,2,6和9为首次从该种植物叶中分离得到。

关键词: 香樟叶, 化学成分, 结构解析, 木脂素, 黄酮

Abstract: Nine compounds were isolated from the 70% ethanol extract of the Cinnamomum camphora leaves by Silica gel column chromatography,polyamide column chromatography,preparative TLC and other isolation techniques.These compounds were identified as dibutyl phthalate(1),l-asarinin(2),(8R,8′R)-3,3′,4,4′-tetramethoxy-9-oxo-8-8′,9-O-9′-lignans(3),quercetin-3-O-β-D-glucopyranoside(4),kaempferol-3-O-β-rutinoside (5),kaempferol-3-O-α-L-rhamnopyr anoside(6),Quercetin-3-O-α-L-rhamnoside(7),rutin(8),isorhamnetin-3-O-β-rutinoside(9) on the basis of the spectral analysis and chemical evidence.Compounds 1,2,6 and 9 were isolated from Cinnamomum camphora Leaves for the first time.

Key words: Cinnamomum camphora leaves, chemical constituents, structure identification, lignans, flavones

中图分类号: 

R284.1