天然产物研究与开发 ›› 2016, Vol. 28 ›› Issue (8): 1244-1250.doi: 10.16333/j.1001-6880.2016.8.013

• 研究简报 • 上一篇    下一篇

利用高碘酸钠氧化制备椰衣醛基纤维

赵斌,黄广民*,王政   

  1. 海南大学食品学院,海口 570228
  • 出版日期:2016-08-30 发布日期:2017-01-17

Preparation of Aldehyde Coir Fiber Via Sodium Periodate Oxidation

ZHAO Bin,HUANG Guang-min*,WANG Zheng   

  1. The Food College of Hainan University,Haikou 570228,China
  • Online:2016-08-30 Published:2017-01-17

摘要: 利用高碘酸钠作为氧化剂,选择性地氧化椰衣纤维上的羟基,使其转化为椰衣醛基纤维。椰衣纤维氧化过程中,采用盐酸羟胺滴定法跟踪测定其醛基的浓度,以考察椰衣纤维的氧化进程。结果表明:当高碘酸钠溶液浓度为0.7 mol/L,氧化温度为50 ℃,氧化时间为3.5 h,高碘酸钠溶液pH为2.8时,氧化效果最佳,椰衣纤维上醛基的量增加,椰衣纤维的结构和功能也将发生了变化,为下一步合成新的椰衣纤维高聚物提供有效的反应点位。

关键词: 盐酸羟胺, 高碘酸钠, 选择性氧化, 醛基椰衣纤维素

Abstract: In this study,sodium periodate was used as oxidant to oxidize the hydroxyl groups on the coir fiber selectively,and to make the coir fiber into a coir aldehyde fiber.During the process of coir fiber oxidation,the hydroxylamine hydrochloride titration was taken to determine the concentration of aldehyde.The results showed that when the concentration of sodium periodate solution was 0.7mol/L,oxidation temperature was 50 ℃,oxidation time was 3.5 h and the pH of sodium periodate solution was 2.8,the oxidation effect was best and the amount of aldehyde group in the coir fiber increased.In addition,the structure and function of coir fiber changed.The results of this study provided foundation for synthesis of new coir fiber polymer in futrue.

Key words: hydroxylamine hydrochloride, sodium periodate, selective oxidation, coir oxidized cellulose

中图分类号: 

TQ352