天然产物研究与开发 ›› 2017, Vol. 29 ›› Issue (4): 601-604.doi: 10.16333/j.1001-6880.2017.4.012

• 研究简报 • 上一篇    下一篇

Au/C催化剂的制备及其对木质素模型化合物的催化氧化研究

耿莉莉,何伟,魏婷,周婷婷,周瑞,张宏喜*   

  1. 昌吉学院化学与应用化学系,昌吉 831100
  • 出版日期:2017-04-29 发布日期:2017-05-08

Preparation and Catalytic Oxidation Performance of Au/C Catalyst for Lignin Model Compound

GENG Li-li,HE Wei,WEI Ting,ZHOU Ting-ting,ZHOU Rui,ZHANG Hong-xi*   

  1. Department of Chemistry and Applied Chemistry,Changji University,Changji 831100,China
  • Online:2017-04-29 Published:2017-05-08

摘要: 以酸处理后的活性炭为载体,采用浸渍法制备了活性炭负载的Au催化剂,研究了该催化剂对木质素模型化合物2-(2-甲氧基苯氧基)-1-苯基乙醇的催化氧化降解反应。结果表明,以甲醇为溶剂,氧气做氧化剂,当反应温度为150 ℃,反应压力为1.0 MP时,Au/C催化剂能较好的降解木质素模型化合物,转化率达到88%,所得主要产物为愈创木酚,并给出了其可能的催化氧化机理。

关键词: Au/C催化剂, 木质素模型化合物, 催化氧化

Abstract: The activated carbon-supported Au catalyst was prepared by the impregnation method using acid-treated activated carbon as the support.The effects of this catalyst in the catalytic oxidative degradation of lignin model compound 2-(2-methoxyphenoxy)-1-phenyl ethanol were investigated.The results revealed that lignin model compound underwent catalytic oxidation to produce guaiacol as the primary product and its conversion yield could reach up to 88% at 150 ℃ and 1.0 MPa using methanol as solvent,oxygen as oxidant.A possible mechanism producing guaiacol was presented.

Key words: Au/C catalyst, lignin model compound, catalytic oxidation

中图分类号: 

TQ351