天然产物研究与开发 ›› 2017, Vol. 29 ›› Issue (5): 826-830.doi: 10.16333/j.1001-6880.2017.5.019

• 开发研究 • 上一篇    下一篇

柠檬渣微波改性及吸附pb2+的性能研究

陈月铃,沈王庆*,朱俊   

  1. 内江师范学院化学化工学院,内江 641112
  • 出版日期:2017-05-31 发布日期:2017-06-09

Modification and pb2+ adsorption Property of Lemon Residues

CHEN Yue-ling,SHEN Wang-qing*,ZHU Jun   

  1. College of Chemistry and Chemical Engineering,Neijiang Normal University,Neijiang 641112,China
  • Online:2017-05-31 Published:2017-06-09

摘要: 为了研究柠檬渣微波改性后的吸附性能,测量了改性柠檬渣对pb2+的吸附率、柠檬渣的比表面积(BET)、灰分、碘吸附值和孔结构;并利用红外光谱(IR)、紫外光谱(UV)、差热分析(TGDTA)、扫描电镜(SEM)和能谱(EDS)对柠檬渣进行了表征。微波改性的柠檬渣对pb2+吸附率比化学改性和预处理后的柠檬渣都有明显增加。与化学改性相比,柠檬渣经微波改性后比表面积有所减小,灰分率增大近5倍,碘吸附值增大近1.5倍;产生羧基和内酯基的量相对较多,酚羟基产生的量相对较少。改性柠檬渣吸附pb2+后,总体骨架没有改变。微波改性柠檬渣在206 nm左右处有最大紫外吸收峰,吸附pb2+后在192 nm左右处出现最大吸收峰。微波改性的柠檬渣和吸附pb2+后的柠檬渣都有三个失重过程,主要由碳组成,pb2+能被改性柠檬渣有效吸附,但pb2+的重量和原子百分比都不高。改性后的柠檬渣表面变得疏松,孔数量明显增加。

关键词: 柠檬渣, 微波, 改性, 吸附

Abstract: In order to study the adsorption properties of lemon residues modified by microwave,the adsorption rates for pb2+,specific surface area(BET),ash rate,iodine adsorption value and pore structure of the modified lemon residue were detected,and the structures of lemon residue were characterized by IR,UV,TGDTA,SEM/EDS. Compared to the lemon residue that was treated chemically and pre-treated,the adsorption rates of lemon residue modified by microwave,increased significantly. Compared to chemical treatment,for the lemon residue modified by microwave,the specific surface area decreased,the ash rate increased by nearly 5 times,and the iodine adsorption value increased by nearly 1.5 times,the amount of carboxyl group and lactones group was relatively large,and the amount of lactones group was relatively small. After the modified lemon residue absorbed pb2+,the overall framework did not change. Before and after absorbing pb2+,the maximum UV absorption peak of the modified lemon residues was about 206 nm and 192 nm,the lemon residue modified by microwave had three weight loss processes,and were mainly composed of carbon. The pb2+ can be adsorbed by the modified lemon residues effectively,but the weight and atomic percentage of pb2+ were not high. The surface of the modified lemon residues became loose,and the number of holes increased obviously.

Key words: lemon residues, microwave, modification, adsorption