地菍的化学成分

天然产物研究与开发 ›› 2010, Vol. 23 ›› Issue (6): 940-944.

地菍的化学成分

杨丹^1,2，马青云³，刘玉清¹，丁中涛²，周俊¹，赵友兴^1*

¹中科院昆明植物研究所植物化学与西部植物资源国家重点实验室，昆明 650204；²中国热带农业科学院热带生物技术研究所，海口 571101；³云南大学，昆明 671001

收稿日期:2008-12-25 出版日期:2011-01-10 发布日期:2011-10-19
通讯作者: yxzhao@mail.kib.ac.cn

Chemical Constituents from Melastoma dodecandrum

杨丹^1,2，马青云³，刘玉清¹，丁中涛²，周俊¹，赵友兴^1*

¹ State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Batany, Chinses Academy of Sciences, Kunming 650204, China;² Institute of Tropical Bioscience and Biotechnology, Chinese Academy of Tropical Agricultural Sciences, Haikou 571101, China; ³Yunnan University, Kunming 671001, China

Received:2008-12-25 Online:2011-01-10 Published:2011-10-19
Supported by:
This work was supported by National Nonprofit Institute Research Grant of CATAS-ITBB (No. 110301) and Natural Science Foundation of Yunnan (2008CD159)

摘要/Abstract

摘要：

为了研究野牡丹科药用植物地菍（Melastoma dodecandrum）的化学成分，采用柱层析方法分离鉴定了15个化合物，通过波谱分析及对比文献等方法鉴定为4-O-β-D-吡喃葡萄糖基-3,3',4'-三甲氧基鞣花酸（1），槲皮素3-O-刺槐二糖苷（2），8-C-吡喃葡萄糖基-5,7,3',4'-四羟基黄酮（3），3-O-β-D-吡喃葡萄糖基-4',5,7-三羟基黄酮（4），6-C-吡喃葡萄糖基-4',5,7-三羟基黄酮（5），3-hydroxy-22(29)-hopen-23-oic acid（6）, 2,3-dihydroxy-9(11)-fernen-23-oic acid（7），3β-sitosterol laminaribioside（8）, 姜糖酯B（9）, 3-O-β-D-galactopyranoside-glycerol1-alkanoates（10），胡萝卜苷（11），β-谷甾醇（12），二十八烷醇（13），二十四烷酸（14）以及三十四烷（15）化合物结构。所有化合物均为首次从该植物中分离得到。

关键词: 地菍, 黄酮, 化学成分

Abstract:

Fifteen compounds were isolated from the ethanol extract of Melastoma dodecandrum. Their structures were elucidated as 4-O-β-D-glucopyranosyl-3,3',4'-tri-O-methylellagic acid (1), quercetin 3-robinobioside (2), 8-C-glucopyranosyl-5,7,3',4'-tetrahydroxyflavone (3), 3-O-β-D-glucopyranosyloxy-4',5,7-trihydroxy flavone (4), 6-C-galactopyranosyl-4',5,7-trihydroxyflavone (5), 3-hydroxy-22(29)-hopen-23-oic acid (6), 2,3-dihydroxy-9(11)-fernen-23-oic acid (7), 3β-sitosterol laminaribioside (8), gingerglycolipid B (9), 3-O-β-D-galactopyranoside-glycerol1-alkanoates (10), daucosterol (11), β-sitosterol (12), octacosanol (13), tetracosanoic acid (14), and tetratriacontane (15) on the basis of spectroscopic analysis and comparison of their spectral data with those of reported. All compounds were isolated from this plant for the first time.

Key words: Melastoma dodecandrum, flavonoids, chemical constituents

杨丹，马青云，刘玉清，丁中涛，周俊，赵友兴. 地菍的化学成分[J]. 天然产物研究与开发, 2010, 23(6): 940-944.

YANG Dan, MA Qing-Yun, LIU Yu-Qing, DING Zhong-Tao, ZHOU Jun, ZHAO You-Xing. Chemical Constituents from Melastoma dodecandrum[J]. NATURAL PRODUCT RESEARCH AND DEVELOPMENT, 2010, 23(6): 940-944.

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